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Video Settings, Frame Rate: The frame rate depends on the length of your clip If you have a 2-second clip, then a setting of 6 fps results in a 12-frame sequence, which is imported into Flash Higher frame rates equal more individual frames that Flash needs to animate Basically, you want to obtain a balance between a minimum number of frames and a smooth, believable sense of movement without the sequence becoming too jerky or jumpy Special Processing: Because the Special Processing dialog gives you a live preview of each effect, you may want to experiment with different settings Noise reduction can smooth pixilated edges, while the de-interlace option averages the lower and upper fields for each frame rendering Otherwise, the field you specified in the New Project settings is used as when rendering the frame.

Side-Chain Alkylation There is continued interest in the alkylation of toluene with methanol because of the potential of the process in practical application to produce styrene 430 Basic catalysts, specifically, alkali cation-exchanged zeolites, were tested in the transformation The alkali cation acts as weak Lewis acid site, and the basic sites are the framework oxygen atoms The base strength and catalytic activity of these materials can be significantly increased by incorporating alkali metal or alkali metal oxide clusters in the zeolite supercages Results up to 1995 are summarized in a review 43o A comparative study with various types of zeolite showed that Cs-exchanged X and Y zeolites were active for toluene alkylation but primarily catalyzed the decomposition of methanol to CO 431 L and Beta zeolites, in turn, were less active and required higher reaction temperature but were much more selective, providing only very little CO.

Adding boron to Cs-exchanged zeolites promotes the alkylation reaction 432 It appears that boron reduces the decomposition of methanol to CO without inhibiting active sites for side-chain alkylation Apparently, zeolites with low basic site densities and appropriate base strength are the selective systems catalyzing toluene side-chain alkylation 432 ,433 In agreement with these observations, KNaX was found to show enhanced catalytic selectivity on proper ball milling 434 Ball milling was suggested to moderately decrease the concentration of both Lewis base and Lewis acid sites At the same time, the density of the strong Brpnsted acid sites that are responsible for ring alkylation decreases significantly Mechanistic studies using solid-state NMR technique with alkali-exchanged X and Y zeolites showed strong interaction between Cs+ ions and toluene435 and the formation of formaldehyde, the apparent alkylating agent.

De-interlacing is not recommended if you are scaling down any DV-format video that you want to convert to an image sequence Meaning, if you re outputting an image sequence at 720 480 (normal DV frame size), then you should turn de-interlace on If you are outputting at any size smaller than the original interlaced video, then leave the de-interlace option off 8 After you specify the settings for the export, you should create a new folder or choose an existing folder to store the image sequence When you name the export, don t worry about adding a number to the file name Premiere does this automatically For example, typing apple_ for the filename directs Premiere to call each frame of the sequence as follow: apple_01, apple_02, apple_03, and so on In Windows, the appropriate file extension is added as well, such as apple_01pct 9.

435 ,436 There is a new report on CsNaX impregnated with CsOH studied under flow conditions by in situ NMR spectroscopy437 It shows that formate species, earlier thought to be responsible for catalyst poisoning, are reactive and contribute as alkylating agent to the process IR spectroscopic investigations indicated that large cations have higher preference to adsorb toluene over methano1 438 The methyl group of toluene interacts with the lattice oxygen and is polarized, which is essential for participation in the alkylation process Rb and Cs are the two cations best satisfying these requirements Some observations indicate that the zeolite framework is a prerequisite for good catalyst performance via physical constraints and proximity of acid-base sites within the molecular sieves environment 431 Other observations show that rather microporosity plays an important role in the alkylation 432 Alkenes may also be used as reagents in side-chain alkylation.

When the ow is highly turbulent multiphase, there are only two practical design options: Static or motionless mixers Valves, nozzles, and ori ce plates